NOTE: This version of Spider-Man wouldn't have really been in Age of Ultron, just like Tom Holland wasn't as Im sure it was too late by the time Sony gave back the rights. Just like he was mentioned in Ant-Man, he would've been here.
We can say that he's moved on from MJ and is now a teacher at Midtown High, and Peter got to go on a date with Gwen, but that didn't last long either mainly because of the events of Spider-Man 3
But from here, Peter is a changed man and we will find out how this Peter Parker would interact with other Marvel Superheroes if he were in Civil War?
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What If Tobey Maguire's Spider-Man Was In Cival War?
FanfictionA while ago, I did one fanfic of Tobey being in the MCU before NWH, here is the next part with Tobey in Civil War