steve rogers: you meet at one of tony starks parties in the avengers tower
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tony stark: he saved you during the attack on sokovia
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thor odinson: you meet through valkyrie, you were looking to get off sakaar so she introduced you to thor and he helped you off the planet and you become a revenger
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clint barton: you worked at Starbucks and he popped in on the way to a mission debriefing
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natasha romanoff: she was on an undercover mission to find a notorious drug dealer and the two of you bump into each other in a club that she'd followed the dealer into
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wanda maximoff: the two of you meet just after you'd had an interview with pepper potts for an internship, you bump into her on the way out
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