If one were to discount Robin (Cobie Smulders), since she is a main character, then the ex-girlfriend of Ted's (Josh Radnor) who has appeared in the most episodes would be Victoria (Ashley Williams), with 16 overall.
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Things You Didn't Know About HIMYM
FanfictionHere are some mind-blowing facts that you probably didn't know about the show How I Met Your Mother.
