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Shah Rukh Khan as Anand Chatterjee -- Indian successful businessman based in London. He grew up in a conservative Bengali Hindu-Brahmin family but living in a modern lifestyle and culture. He loves his family by being a strict father and husband. All his secrets are with his wife, Alena. But there's one thing he is hiding. And he had no intention of revealing it to anyone. Not even to Alena.
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Kajol as Alena Chatterjee -- Anand was the campus casanova till he met this now-Nobel Prize-winning writer. Inherited Indian-British blood, she is a simple wife and mother who loves only two things in this world, her family and her job. She thought Anand had shared all his secrets with her but it's not. And that made her suffer.
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Jibraan Khan as Aditya Chatterjee -- The only heir of the Chatterjee. After completing his MBA he managed his family company along with his father. He got his father's charm and his mother's brilliant mind. He is innocent yet has to pay the biggest sin of his father.
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Rani Mukherji as Pallavi -- Indian girl who came abroad to pursue her study. Her friends took her into the darkest world she had ever encountered. She had an unfinished past, just like Anand. For her, there was only one man and there would be forever.
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Ranbir Kapoor as Farozi Pathan -- Anand's personal assistant who's in a complicated love story. Break-up threat from his materialist girlfriend makes him have to work double shifts to fulfill the mad girl's request. He took advantage of the ability passed down by his grandfather to earn money. He later became friends with Armaan for doing the same job.
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Siddharth Malhotra as Armaan -- An innocent young man who tried his luck in London to pay for his sister's college and his ill mother's treatment. He does a lot of work to earn more money. He owes Farozi for that. He introduced him to the business of two worlds.
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Tabu as Sona -- Alena's childhood best friend. The psychologist who was the first to notice something strange about the family. She is also the one who introduces Anand and Alena to Indrani.
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